Heats and kinetics of oxidation of small copper particles in copper-containing catalysts

descriptionPublicationkeyboard_double_arrow_right Article 01 Jul 1984 Italy English Publisher:Springer Science and Business Media LLCJournal:Journal of Thermal Analysis, volume 29, pages 655-663 (issn: 0368-4466, eissn: 1572-8943,

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Authors: FUBINI, Bice; GIAMELLO, Elio;

doi: 10.1007/bf01913522

handle: 2318/113749

Heats and kinetics of oxidation of small copper particles in copper-containing catalysts

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Abstract

The r.t. interaction of oxygen with finely-divided copper in Cu/ZnO catalysts has been studied by gas-solid microcalorimetry. The oxidation is accompanied by the presence of a pseudo-equilibrium pressure, which increases as the reaction proceeds. Surface and several subsurface layers are involved, but a metallic core is always left.

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Italy

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University of Turin
Italy

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