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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Rheologica Actaarrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Rheologica Acta
Article . 1986 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
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Determination of molar mass polydispersity index from dynamic rheological measurements

Authors: G. Couarraze; J. L. Grossiord; F. Puisieux;

Determination of molar mass polydispersity index from dynamic rheological measurements

Abstract

The polydispersity of the molar mass of a material influences the behaviour of its dynamic rheological propertiesG′ (ω) andG″ (ω). This is exemplified by the deviation from unity of the indexI = [2 − (d logG′/d logω)]/[1 − (d logG″/d logω)] in the terminal zone, i.e. at low frequencies. For a normal logarithmic distribution of species, a quantitative correlation may be established between the rheological properties and the parameter that is characteristic of the polydispersity for these species. This correlation can, in certain cases, be drawn from measurements in just the terminal zone or it may require measurements both in the terminal zone and at the beginning of the plateau zone. In each case, the parameter of dispersion can be determined by simple graphical or numerical methods. Finally, an example of the application of these methods to entangled liquid polymers is presented.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
5
Average
Average
Average
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