Redox reactions between organic halo-compounds and ferrous cations in isopropanol

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1978 English Publisher:Springer Science and Business Media LLCJournal:Transition Metal Chemistry, volume 3, pages 172-174 (issn: 0340-4285, eissn: 1572-901X,

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Authors: Liliane Wilputte-Steinert;

doi: 10.1007/bf01393538

Redox reactions between organic halo-compounds and ferrous cations in isopropanol

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Abstract

Halo-compounds of which the half-wave reduction potential is equal to or less negative than that of carbon tetrachloride, are reduced by tetrachloroferrate(II) anions. The bimolecular rate constants measured at 250 in isopropanol are 2 × 10−5 M−1 s−1 and 1 × 10−4 M−1 s−1 respectively for CCl4 and CCl3CO2Me.

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Université Libre de Bruxelles
Belgium

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