Oxide anodes in electro-organic oxidation. Oxidation of maleic addon tungsten oxide anodes

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 1982 English Publisher:Springer Science and Business Media LLCJournal:Journal of Applied Electrochemistry, volume 12, pages 127-133 (issn: 0021-891X, eissn: 1572-8838,

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Authors: G. Filardo; F. Di Quarto; S. Gambino; G. Silvestri;

doi: 10.1007/bf01112074

Oxide anodes in electro-organic oxidation. Oxidation of maleic addon tungsten oxide anodes

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Abstract

The electrochemical oxidation of maleic acid on tungsten anodes has been investigated. Glyoxal and carbon dioxide were the main products together with tartaric acid and acetaldehyde. Glyoxal is also obtained as the main product from the oxidation ofd-tartaric acid. Under the same conditions succinic acid is completely oxidized to carbon dioxide and water. The anodic dissolution of tungsten and the oxidation of water to oxygen become predominant in the final stages of the electrolyses.

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University of Palermo
Italy

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