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image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Journal of Solution ...arrow_drop_down
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
Journal of Solution Chemistry
Article . 1973 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
image/svg+xml Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao Closed Access logo, derived from PLoS Open Access logo. This version with transparent background. http://commons.wikimedia.org/wiki/File:Closed_Access_logo_transparent.svg Jakob Voss, based on art designer at PLoS, modified by Wikipedia users Nina and Beao
https://doi.org/10.1007/978-1-...
Part of book or chapter of book . 1973 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
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Toward a model for liquid water

Authors: Julian H. Gibbs; Claude Cohen; Paul D. Fleming; Harold Porosoff;

Toward a model for liquid water

Abstract

A new model is proposed for liquid water. It is obtained by consideration of the two transitions (melting and boiling) which define the liquid phase. These transitions are discussed with the aid of two analogies to well-known phenomena in polymer physical chemistry. In analogy to the helix-coil transition in polypeptides and polynucleotides, the melting of ice is viewed as a process consisting essentially of the destruction of the orderly interconnected small rings of hydrogen bonds characteristic of the crystal. The fact that the breakup of interconnected small rings is cooperative, even when unaccompanied by the breaking of bonds which are not parts of rings, is clearly seen by inspection of the theory for the putatively analogous helix-coil transition. The condensation of water vapor is viewed in analogy to gelation in reversibly polymerizing systems, an analogy which interprets its cooperativity. Taken together, these interpretations of the phase transitions indicate that the liquid can be viewed as an infinitely and randomly branched “gel” of (rapidly interchanging) hydrogen bonds in which closures of rings (primarily large rings) are present at random but in which there is no significant preference for an ordered array of small rings. These concepts also lead naturally to an interpretation of the triple point and sublimation. The random gel model is seen to be consistent with most of the known properties of liquid water. In particular, the radial distribution function, infrared and Raman spectra, dielectric properties, density maximum, and properties of the supercooled region are discussed briefly here.

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
29
Average
Top 10%
Top 10%
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