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Article . 1994
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Journal of Applied Electrochemistry
Article . 1994 . Peer-reviewed
License: Springer TDM
Data sources: Crossref
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Electrolysis of MgCl2 with a top inserted anode and an Mg-Pb cathode

Authors: Güden, Mustafa; Karakaya, İshak;

Electrolysis of MgCl2 with a top inserted anode and an Mg-Pb cathode

Abstract

High energy consumption in the production of magnesium by molten salt electrolysis is mainly due to the recombination of magnesium and chlorine. The large interelectrode distance used, in conventional techniques, to reduce the extent of ‘back reaction’, results in a significant potential drop. A laboratory cell that enables the operation with smaller interelectrode distance and easy separation of electrode products has been used to study electrolytic magnesium production. The cell features a top inserted graphite anode and a Mg-Pb alloy cathode at the bottom. Current efficiency and power consumption were determined at 690° C using a current density of 0.48 A cm−2. Experiments were performed to study the effects of MgCl2 concentration and anode-cathode distance (a.c.d.) on cell operation. Results indicated that an electrolyte containing 20% MgCl2 (equiweight NaCl:KCl and 1 % NaF) with a 3 cm a.c.d. reduced the cell voltage to 3.72 V. This value corresponds to an energy consumption of 11.3 kWh kg−1 including the refining of Mg-Pb alloy produced at the cathode. This cell performance is more energy efficient compared to conventional magnesium cells.

Country
Turkey
Keywords

Magnesium, Chlorine, Electrolytic cells

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
9
Average
Top 10%
Average
Green
bronze