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Time-resolved spectroscopy and energy transfer in Pr3+-doped Gd2(SO4)3�8H2O

descriptionPublicationkeyboard_double_arrow_right Article 01 Jul 1995 English Publisher:Springer Science and Business Media LLCJournal:Applied Physics A Materials Science and Processing, volume 61, pages 177-181 (issn: 0947-8396, eissn: 1432-0630,

Authors: B. C. Grabmaier; E. Bayer; G. Blasse; J. Leppert;

doi: 10.1007/bf01538386 , 10.1007/s003390050187

Time-resolved spectroscopy and energy transfer in Pr3+-doped Gd2(SO4)3�8H2O

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Abstract

The luminescence of Pr3+ in gadolinium sulfate hydrate is reported for 195 nm laser excitation. the Pr3+ ion acts as a sensitizer of the host lattice emission. The Pr3+→Gd3+ energy transfer occurs in two different ways. In the octahydrate the transfer occurs from the lowest component of the 4f5d configuration of Pr3+, but in the samples with less water there is energy transfer from the1So level of Pr3+ to several Gd3+ levels. The Pr3+ emission in the two modifications is, of course, also strikingly different.

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