Organogallium-Selenium Compounds

descriptionPublicationkeyboard_double_arrow_right Part of book or chapter of book , Other literature type 01 Jan 1986 English Publisher:Springer Berlin Heidelberg

Authors: Jean-Claude Maire; Ulrich Krüerke; Marlis Mirbach; Wolfgang Petz; Christa Siebert;

doi: 10.1007/978-3-662-07374-2_7

Organogallium-Selenium Compounds

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Abstract

Ga(CH3)2SeCH3 is obtained as a nonvolatile solid by condensation of Ga(CH3)3 on CH3SeH (1:1 mole ratio). The dimeric product melts at 119 to 120°C. The vapor pressure has been determined in the 120 to 140°C range to give the equation log (p/Torr) = 9.63–3450/T and ?HV=16 kcal/mol. The compound is dimeric in the vapor phase. Above 160°C decomposition occurs with formation of a non-condensable gas. With N(CH3)3 a 1:1 adduct is formed [1].

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Aix-Marseille University
France
Aix-Marseille University
France

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