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Steroidal quinoxalines

Name: Steroidal quinoxalines
Creator: Catsoulacos, P.
Keywords: 01 natural sciences, 0104 chemical sciences, 3. Good health

descriptionPublicationkeyboard_double_arrow_right Article 01 Dec 1973 Greece English Publisher:WileyJournal:Journal of Heterocyclic Chemistry, volume 10, pages 933-934 (issn: 0022-152X, eissn: 1943-5193,

Authors: Catsoulacos, P.;

doi: 10.1002/jhet.5570100608

Steroidal quinoxalines

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Abstract

AbstractThe treatment of 3β‐hydroxy‐16α‐bromo‐5α‐androstan‐17‐one, 3β‐acetoxy‐16α‐bromo‐5‐androsten‐17‐one and 21‐bromo‐5‐pregnen‐3β‐ol‐20‐one with 4,5‐dimethyl‐o‐phenylenediamine gave substituted quinoxalines.Hydrolysis of 3β‐acetoxy‐5‐androsteno[16,17‐b]‐6′,7′‐dimethylquinoxaline produced the corresponding 3β‐hydroxy compound. 3‐Oxo‐4‐androsteno[16,17‐b]‐6′,7′‐dimethylquinoxaline was obtained by Oppenauer oxidation of the corresponding alcohol.

Country

Greece

Related Organizations

National and Kapodistrian University of Athens
Greece

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