Chitooligosaccharide Synthesis Using an Ionic Tag
Copyright policy )Chitooligosaccharide Synthesis Using an Ionic Tag
AbstractAn environmentally improved synthesis of the N‐differentiated chitotetrasaccharide CO‐IV‐(NH2), a key intermediate for the preparation of lipochitooligosaccharides and the TMG‐chitotriomycin, is reported based on a chromatography‐free ionic‐liquid tagging approach. The method involves the glycosylation of ionic‐liquid‐tagged acceptors with thioglucosamine donors leading to the stereoselective formation of β‐(1→4)‐linked glucosamine‐containing oligomers.
Glycosylation, [SPI.GPROC] Engineering Sciences [physics]/Chemical and Process Engineering, [SDV]Life Sciences [q-bio], Carbohydrates, 500, [SDV.IDA] Life Sciences [q-bio]/Food engineering, 540, Ionic liquids, [SDV] Life Sciences [q-bio], Synthetic methods, [SDV.IDA]Life Sciences [q-bio]/Food engineering, [SDV.BV]Life Sciences [q-bio]/Vegetal Biology, [SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering, [SDV.BV] Life Sciences [q-bio]/Vegetal Biology, Protecting groups
Glycosylation, [SPI.GPROC] Engineering Sciences [physics]/Chemical and Process Engineering, [SDV]Life Sciences [q-bio], Carbohydrates, 500, [SDV.IDA] Life Sciences [q-bio]/Food engineering, 540, Ionic liquids, [SDV] Life Sciences [q-bio], Synthetic methods, [SDV.IDA]Life Sciences [q-bio]/Food engineering, [SDV.BV]Life Sciences [q-bio]/Vegetal Biology, [SPI.GPROC]Engineering Sciences [physics]/Chemical and Process Engineering, [SDV.BV] Life Sciences [q-bio]/Vegetal Biology, Protecting groups
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