Selective Glycerol Oxidation by Electrocatalytic Dehydrogenation
Copyright policy )Selective Glycerol Oxidation by Electrocatalytic Dehydrogenation
AbstractThis study demonstrates that an electrochemical dehydrogenation process can be used to oxidize glycerol to glyceraldehyde and glyceric acid even without using stoichiometric chemical oxidants. A glyceric acid selectivity of 87.0 % at 91.8 % glycerol conversion was obtained in an electrocatalytic batch reactor. A continuous‐flow electrocatalytic reactor had over an 80 % high glyceric acid selectivity at 10 % glycerol conversion, as well as greater reaction rates than either an electrocatalytic or a conventional catalytic batch reactor.
- University of Massachusetts Amherst United States
- Gwangju Institute of Science and Technology Korea (Republic of)
- University of Wisconsin–Oshkosh United States
- Pohang University of Science and Technology Korea (Republic of)
- University of Massachusetts System United States
Glycerol, energy conversion, MEMBRANE REACTOR, FUEL-CELLS, Catalysis, BIOMASS, Electrochemistry, PLATINUM-BISMUTH CATALYST, ALDEHYDES, Temperature, METAL-CATALYSTS, ALCOHOLS, Hydrogen-Ion Concentration, biofuels, PRODUCTS, CONVERSION, BIMETALLIC CATALYSTS, heterogeneous catalysis, electrochemistry, oxidation reaction, Hydrogenation, Oxidation-Reduction
Glycerol, energy conversion, MEMBRANE REACTOR, FUEL-CELLS, Catalysis, BIOMASS, Electrochemistry, PLATINUM-BISMUTH CATALYST, ALDEHYDES, Temperature, METAL-CATALYSTS, ALCOHOLS, Hydrogen-Ion Concentration, biofuels, PRODUCTS, CONVERSION, BIMETALLIC CATALYSTS, heterogeneous catalysis, electrochemistry, oxidation reaction, Hydrogenation, Oxidation-Reduction
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