Photoinduced Symmetry‐Breaking Charge Separation
Copyright policy )Photoinduced Symmetry‐Breaking Charge Separation
AbstractMolecular systems where several apparently equivalent charge separation pathways exist upon photoexcitation are presented. They encompass MQn (n≥2) architectures, where M is a chromophore and Q an electron transfer quencher (either donor or acceptor), and M–M systems where M acts as both electron donor and acceptor. In all cases, charge separation involves symmetry breaking. The conditions for such process to be operative as well as the origin of the symmetry breaking are discussed.
- University of Geneva Switzerland
Photochemistry, Multichromophoric systems, Photoinduced electron transfer, 540, Excitation energy hopping, Ultrafast spectroscopy, ddc: ddc:540
Photochemistry, Multichromophoric systems, Photoinduced electron transfer, 540, Excitation energy hopping, Ultrafast spectroscopy, ddc: ddc:540
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