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Research@WUR
Article . 2014
License: CC BY NC ND
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Biofuels Bioproducts and Biorefining
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Biofuels Bioproducts and Biorefining
Article . 2014 . Peer-reviewed
License: Wiley Online Library User Agreement
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Green building blocks for bio‐based plastics

Authors: Harmsen, P.F.H.; Hackmann, M.M.; Bos, H.L.;

Green building blocks for bio‐based plastics

Abstract

Abstract In this paper we investigate the possible routes to produce the most commonly used polymers from biomass. This includes vinyl polymers, polyesters, polyamides, polyurethanes, and synthetic rubbers. Also the most promising newly developed polymers that can be produced from biomass are investigated. Approximately 80% by weight of all chemicals produced by the petrochemical industry are applied in polymer materials. Producing these materials from biomass instead of fossil resources thus significantly contributes to the development of the bio‐based economy. We show that it is technically possible to produce all major bioplastics from biomass. In many cases even more than one process can be envisioned. Essential chemical building blocks involved in the bio‐based production routes are presented, including state of the art production routes and production volumes. If we assume that processing costs for bio‐based processes will lower with further development of the bio‐based technologies, feedstock costs will start to weigh more heavily on the total production costs in the future. In that respect efficient use of biomass will become more important. Building blocks with acid‐ and alcohol functionalities, such as lactic acid and succinic acid, can be well produced from biomass like sugars, since the oxygen atoms needed for these building blocks are already present in the biomass. Building blocks that can be applied in many polymer groups due to their chemical structure are promising and are expected to undergo substantial growth. We show that there are various developments on these versatile building blocks. © 2014 Society of Chemical Industry and John Wiley & Sons, Ltd

Country
Netherlands
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Keywords

bulk chemicals

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    Impact byBIP!
    selected citations
    These citations are derived from selected sources.
    This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    249
    popularity
    This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
    Top 1%
    influence
    This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
    Top 1%
    impulse
    This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
    Top 1%
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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
249
Top 1%
Top 1%
Top 1%
Green
hybrid