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Journal of Applied Polymer Science
Article . 2024 . Peer-reviewed
License: CC BY
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https://doi.org/10.2139/ssrn.4...
Article . 2023 . Peer-reviewed
Data sources: Crossref
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Biodegradable polybutylene adipate terephthalate foams: Investigating sustainability via reprocessing and green solvent

Investigating sustainability via reprocessing and green solvent
Authors: Guilherme de Macedo Rooweder Lima; Simon F. H. Hobbenschot; Adrivit Mukherjee; Daniele Parisi; Francesco Picchioni; Ranjita K. Bose;

Biodegradable polybutylene adipate terephthalate foams: Investigating sustainability via reprocessing and green solvent

Abstract

AbstractIncorporating reprocessing, recycling, and sustainable processes and materials is essential for a circular economy. Reprocessing and recycling are related since both help minimize wastage and produce a sustainable regenerative economy. However, polymers might undergo degradation depending on the recycling process, reducing their lifespan. In this study, polybutylene adipate terephthalate (PBAT) undergoes repetitive reprocessing under varied temperatures, times, and shear rates to investigate the evolution of mechanical, chemical, and thermal properties. Furthermore, foaming experiments are conducted using supercritical carbon dioxide (scCO2) on reprocessed samples to examine changes in the properties and morphology of the foam. The significance of reprocessing PBAT is divided into environmental, temperature, and processing effects. Environmental conditions impact the results where no oxidation effects are noticed in the 2‐hour test, while 7 days of humidity exposure lead to a tenfold reduction in polymer viscosity. Different processing techniques reduce the molecular weight of PBAT and alter its polydispersity. Specifically, the number average molecular weight (Mn) decreases from an initial 53 to 37 kDa after processes like extrusion or mixing. However, elongation at break and ultimate strength of PBAT remain unchanged after high‐shear extrusion processing. Additionally, PBAT foam morphology evolves over 5 cycles, leading to smaller pores and reducing compressive modulus.

Country
Netherlands
Related Organizations
Keywords

supercritical CO, foaming, biodegradable, PBAT, reprocessing

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
2
Average
Average
Average
hybrid