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Journal of Applied Polymer Science
Article . 2015 . Peer-reviewed
License: Wiley Online Library User Agreement
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Film blowing of PHBV blends and PHBV‐based multilayers for the production of biodegradable packages

Authors: Mara Cunha; Bruno Fernandes; José A. Covas; António A. Vicente; Loïc Hilliou;

Film blowing of PHBV blends and PHBV‐based multilayers for the production of biodegradable packages

Abstract

ABSTRACTPoly(hydroxy butyrate‐co‐valerate) (PHBV) is a biodegradable polymer that is difficult to melt process into films. Such difficulty is mirrored in the lack of literature on film blowing of PHBV‐ or PHBV‐based materials. To circumvent this problem, 70/30 wt % blends of PHBV with a biodegradable compound (PBSebT), or with poly(butylene adipate‐co‐terephtalate) (PBAT), were prepared and tested for extrusion film blowing. Both blends showed a similar rheological pattern at 175°C, which is the maximum processing temperature with tolerable thermal degradation. Blending stabilized the film bubbles, thus widening the processing window. However, film properties such as tensile modulus, strain at break and tear resistance remained isotropic and crystallinity characteristics in the machine and transverse directions were generally similar. To bypass the thermal degradation associated with polymer blending, PHBV/PBAT films were coextruded. These showed enhanced functional properties when compared with films blown from blends. The mechanical properties of bilayered films matched those of films blown from commercial PBAT designed for food packaging. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 42165.

Country
Portugal
Related Organizations
Keywords

Packaging, Biodegradable, Rheology, Films

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
views
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64
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