
AbstractAqueous solutions of p‐nitrobenzoic acid were hydrogenated in the presence of Pt/C and Pd/C catalysts in a slurry reactor. External as well as internal mass transport steps were studied using a membrane H2‐electrode and a metal probe electrode. After the influence of the mass transport effects was corrected for, it was possible to obtain corrected values of the kinetic characteristics of the overall chemical reaction. The mechanism was studied using potential and polarization methods.
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