C−H Reactivity of the α‐Position in Nitrones and Nitronates

descriptionPublicationkeyboard_double_arrow_right Article 10 Oct 2019 English Publisher:WileyJournal:Advanced Synthesis & Catalysis, volume 362, pages 724-754 (issn: 1615-4150, eissn: 1615-4169,

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Authors: Alexey Yu. Sukhorukov;

doi: 10.1002/adsc.201900718

C−H Reactivity of the α‐Position in Nitrones and Nitronates

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Abstract

AbstractThe review summarizes the chemistry of nitrones and nitronates in the context of the C−H reactivity of their α‐carbon atoms. Electrophilic, nucleophilic and radical reactions leading to functionalization of the α‐position are described. Examples of the application of these processes in total synthesis are outlined.magnified image

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