The past decade has witnessed significant advances in the field of organic solar cells (OSCs). Ongoing improvements in the power conversion efficiency of OSCs have been achieved, which were mainly attributed to the design and synthesis of novel conjugated polymers with different architectures and functional moieties. Among various conjugated polymers, the development of wide‐bandgap (WBG) polymers has received less attention than that of low‐bandgap and medium‐bandgap polymers. Here, we briefly summarize recent advances in WBG polymers and their applications in organic photovoltaic (PV) devices, such as tandem, ternary, and non‐fullerene solar cells. Addtionally, we also dissuss the application of high open‐circuit voltage tandem solar cells in PV‐driven electrochemical water dissociation. We mainly focus on the molecular design strategies, the structure‐property correlations, and the photovoltaic performance of these WBG polymers. Finally, we extract empirical regularities and provide invigorating perspectives on the future development of WBG photovoltaic materials.