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Geophysical Research Letters
Article . 2015 . Peer-reviewed
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https://dx.doi.org/10.48550/ar...
Article . 2015
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Thermoelasticity of Fe2+‐bearing bridgmanite

Authors: Shukla G.; Wu Z.; Hsu H.; Floris A.; Cococcioni M.; Wentzcovitch R. M.;

Thermoelasticity of Fe2+‐bearing bridgmanite

Abstract

AbstractWe present local density approximation augmented by the Hubbard‐type correction calculations of high‐temperature elastic properties of bridgmanite with composition for 0≤×≤0.125. Results of elastic moduli and acoustic velocities for the Mg end‐member (x=0) agree very well with the latest high‐pressure and high‐temperature experimental measurements. In the iron‐bearing system, we focus particularly on the change in thermoelastic parameters across the state change that occurs in ferrous iron above ∼30 GPa, often attributed to a high‐spin (HS) to intermediate‐spin (IS) crossover but explained by first‐principles calculations as a lateral displacement of substitutional iron in the perovskite cage. We show that the measured effect of this change on the equation of state of this system can be explained by the lateral displacement of substitutional iron and not by the HS to IS crossover. The calculated elastic properties of along an adiabatic mantle geotherm somewhat overestimate longitudinal velocities but produce densities and shear velocities quite consistent with the Preliminary Reference Earth Model data throughout most of the lower mantle.

Countries
Switzerland, Italy, United Kingdom
Keywords

Condensed Matter - Materials Science, 550, F690 - Geology not elsewhere classified, iron-bearing bridgmanite, Equations of state, Materials Science (cond-mat.mtrl-sci), FOS: Physical sciences, NotOAChecked, Physical thermodynamics, thermoelasticity, Geophysics, High-pressure behaviour, General Earth and Planetary Sciences, Anelasticity

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
60
Top 10%
Top 10%
Top 10%
Green
gold