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https://doi.org/10.1117/12.220...
Article . 2015 . Peer-reviewed
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Calculation of the water vapor line intensities for rotational transitions between high-excited energy levels

Authors: Egorov, Oleg V.; Voitsekhovskaya, Olga K.; Kashirskii, Danila E.;

Calculation of the water vapor line intensities for rotational transitions between high-excited energy levels

Abstract

ABSTRACT The intensities of water vapor in the range of pure rotational transitions were calculated up to high quantum numbers(J max ~ 30 and K amax ~ 25). The diagonalization of the effective rotational Hamiltonian, approximated by Pade-Borelmethod, is applied to obtain the eigenv ectors. The centrifugal dist ortion perturbations in line intensities were taken into account by the traditional equatio ns for matrix elements of the transformed dipole moment, including eight parameters,and previously developed by authors Pade approximant. Moreover, to conduct the calculations, the rotationalwavefunctions of the symmetric rotor molecule were applied. The results were compared with the known theoretical data. Water vapor, high-temperature spectra, centrifugal distortion effects, Pade-Borel approximants, symmetric rotors 1. INTRODUCTION At present a large amount of theoretical and experimental publications deal with water vapor (H 2 O) spectra in terahertzand infrared ranges. The results of some works are presented in well-known spectroscopic databases such asHITRAN2012 [1] and HITEMP2010 [2].The strong centrifugal distortion effects are inherent for H

Keywords

спектры высокотемпературные, водяной пар, центробежное искажение, Паде-Бореля аппроксимация, волчки симметричные

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Citations provided by BIP!
popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
0
Average
Average
Average
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