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Interaction of pentaphenylantimony with acetylenedicarboxylic acid. Molecular structure of bis(tetraphenylantimony) acetylenedicarboxilate

descriptionPublicationkeyboard_double_arrow_right Article 01 Jan 2015Publisher:FSAEIHE South Ural State University (National Research University)Journal:«Bulletin of the South Ural State University series "Chemistry"», volume 15, pages 17-22 (issn: 2076-0493, eissn: 2412-0413, Copyright policy )
Authors: SHARUTIN V.V.; SHARUTINA O.K.; GUBANOVA YU.O.;

doi: 10.14529/chem150405

Interaction of pentaphenylantimony with acetylenedicarboxylic acid. Molecular structure of bis(tetraphenylantimony) acetylenedicarboxilate

Abstract

Bis(tetraphenylantimony) acetylenedicarboxilate (1) has been synthesized by the interaction of pentaphenylantimony with acetylenedicarboxylic acid (mole ratio 2:1 or 1:1) in toluene. In molecule 1 the acid anion has the bridging role and bonds Ph4Sbfragments. The antimony atoms have distorted trigonal bipyramidal coordination with the oxygen atom in the axial position. The Sb–O bond lengths are 2.287(4) and 2.389(4) Å, the Sb–C bond lengths are 2.110(7)2.179(6) Å and 2.108(6)2.165(6) Å. Взаимодействием пентафенилсурьмы с ацетилендикарбоновой кислотой (2:1 или 1:1 мольн.) в толуоле получен цетилендикарбоксилат бис(тетрафенилсурьмы) (1). В молекуле 1 остаток кислоты выполняет мостиковую функцию, соединяя фрагменты Ph4Sb. Атомы сурьмы имеют искаженную тригонально-бипирамидальную координацию с атомом кислорода в аксиальном положении. Длина связей SbO 2.287(4) и 2.389(4) Å, SbC 2.110(7)2.179(6) Å и 2.108(6)2.165(6) Å. V.V. Sharutin, vvsharutin@rambler.ru O.K. Sharutina, sharutinao@mail.ru Yu.O. Gubanova, ulchik_7757@mail.ru South Ural State University, Chelyabinsk, Russian Federation. Шарутин Владимир Викторович – доктор химических наук, профессор, старший научный сотрудник УНИД, Южно-Уральский государственный университет. 454080, г. Челябинск, пр. им. В.И. Ленина, 76. E-mail: vvsharutin@rambler.ru Шарутина Ольга Константиновна – доктор химических наук, профессор, кафедра аналитической химии, Южно-Уральский государственный университет. 454080, г. Челябинск, пр. им. В.И. Ленина, 76. E-mail: sharutinao@mail.ru Губанова Юлия Олеговна – студент химического факультета, Южно-Уральский государственный университет. 454080, г. Челябинск, пр. им. В.И. Ленина, 76. E-mail:ulchik_7757@mail.ru

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Keywords

рентгеноструктурный анализ, ацетилендикарбоновая кислота, ГРНТИ 31.21, УДК 547.584, acetylenedicarboxylic acid, УДК 549.242, molecular structure, пентафенилсурьма, ацетилендикарбоксилат бис(тетрафенилсурьмы), bis(tetraphenylantimony) acetylenedicarboxilate, X-ray diffraction analysis, pentaphenylantimony, УДК 548.312.5, PENTAPHENYLANTIMONY,ACETYLENEDICARBOXYLIC ACID,BIS(TETRAPHENYLANTIMONY) ACETYLENEDICARBOXILATE,MOLECULAR STRUCTURE,X-RAY DIFFRACTION ANALYSIS,ПЕНТАФЕНИЛСУРЬМА,АЦЕТИЛЕНДИКАРБОНОВАЯ КИСЛОТА,АЦЕТИЛЕНДИКАРБОКСИЛАТ БИС(ТЕТРАФЕНИЛСУРЬМЫ),МОЛЕКУЛЯРНАЯ СТРУКТУРА,РЕНТГЕНОСТРУКТУРНЫЙ АНАЛИЗ, молекулярная структура, УДК 547.53.024

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selected citations
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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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