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SEPARATION AND PHYSICOCHEMICAL ANALYSIS OF IODINE CONTAINED IN HAUDAK GROUND SALT WATERS ON THE BASIS OF STARCH.

Authors: Uralov Nuriddin Bekmuradovich; Turayev Khayit Khudaynazarovich; Djalilov Abdulahat Turapovich; Normurodov Bakhtiyor Abdullayevich; Karimov Mas`Ud Ubaidullayevich;

SEPARATION AND PHYSICOCHEMICAL ANALYSIS OF IODINE CONTAINED IN HAUDAK GROUND SALT WATERS ON THE BASIS OF STARCH.

Abstract

{"references": ["1.\tGamon, J., Haller, S., Guilmeau, E., Maignan, A., Le Mercier, T., & Barboux, P. Mechanochemical synthesis of iodine-substituted BiCuOS. Journal of Solid State Chemistry, (2018). 263, 157\u2013163. doi:10.1016/j.jssc.2018.04.0112.", "2. I.A. Umbarov Integrated processing of natural groundwater // materials of the Republican scientific and technical conference mining and metallurgical complex: achievements, problems and prospects of innovative development. Navoi. November 15-16, 2016. \u2013 P. 366 (in Russian).", "3.\t I.A. Umbarov, Kh.Kh. Turaev. Study of the kinetics of oxidation of iodide ions in hydrothermal waters by various oxidizing agents. Uzbek Chemical Journal, No. 6, (2015), pp. 12 - 16 (in Russian).", "4.\t\u0423\u043c\u0431\u0430\u0440\u043e\u0432 \u0418.\u0410., \u0422\u0443\u0440\u0430\u0435\u0432 \u0425.\u0425. \u041e\u043f\u0440\u0435\u0434\u0435\u043b\u0435\u043d\u0438\u0435 \u044d\u043b\u0435\u043c\u0435\u043d\u0442\u043d\u043e\u0433\u043e \u0441\u043e\u0441\u0442\u0430\u0432\u0430 \u043f\u043e\u0434\u0437\u0435\u043c\u043d\u044b\u0445 \u0441\u043e\u043b\u0435\u043d\u044b\u0445 \u0432\u043e\u0434// Science Time. \u2013\u041a\u0430\u0437\u0430\u043d\u044c. - 2018. - \u2116 2 \u0421.- 76-80.", "5.\t\u041a\u0443\u043b\u043c\u0430\u0442\u043e\u0432 \u0420.\u0410., \u0423\u043c\u0431\u0430\u0440\u043e\u0432 \u0418., \u0422\u0443\u0440\u0430\u0435\u0432 \u041d.\u0419., \u042d\u0448\u0430\u043d\u0445\u043e\u0434\u0436\u0430\u0435\u0432 \u0421. \u0421\u043e\u0434\u0435\u0440\u0436\u0430\u043d\u0438\u0435 \u0438 \u0444\u043e\u0440\u043c\u0430 \u043d\u0430\u0445\u043e\u0436\u0434\u0435\u043d\u0438\u044f \u0439\u043e\u0434\u0430 \u0432 \u043f\u043e\u0434\u0437\u0435\u043c\u043d\u044b\u0445 \u0441\u043e\u043b\u0435\u043d\u044b\u0445 \u0432\u043e\u0434\u0430\u0445 \u0421\u0443\u0440\u0445\u0430\u043d\u0434\u0430\u0440\u044c\u0438\u043d\u0441\u043a\u043e\u0439 \u043e\u0431\u043b\u0430\u0441\u0442\u0438 // \u0423\u0437\u0431. \u0445\u0438\u043c. \u0436\u0443\u0440. -2000. -\u2116 1. -\u0421. 70-72.", "6.\t\u0423\u043c\u0431\u0430\u0440\u043e\u0432 \u0438\u0431\u0440\u0430\u0433\u0438\u043c \u0430\u043c\u043e\u043d\u043e\u0432\u0438\u0447, \u0423\u0441\u043e\u0432\u0435\u0440\u0448\u0435\u043d\u0441\u0442\u0432\u043e\u0432\u0430\u043d\u0438\u0435 \u0442\u0435\u0445\u043d\u043e\u043b\u043e\u0433\u0438\u0438 \u0432\u044b\u0434\u0435\u043b\u0435\u043d\u0438\u044f \u0439\u043e\u0434\u0430 \u0438\u0437 \u0439\u043e\u0434\u043d\u044b\u0445 \u0441\u043e\u0435\u0434\u0438\u043d\u0435\u043d\u0438\u0439, \u0441\u043e\u0434\u0435\u0440\u0436\u0430\u0449\u0438\u0445\u0441\u044f \u0432 \u043f\u043e\u0434\u0437\u0435\u043c\u043d\u044b\u0445 \u0441\u043e\u043b\u0435\u043d\u044b\u0445 \u0432\u043e\u0434\u0430\u0445. \u0414\u0438\u0441\u0441\u0435\u0440\u0442\u0430\u0446\u0438\u044f \u043d\u0430 \u0441\u043e\u0438\u0441\u043a\u0430\u043d\u0438\u0435 \u0443\u0447\u0435\u043d\u043e\u0439 \u0441\u0442\u0435\u043f\u0435\u043d\u0438 \u0434\u043e\u043a\u0442\u043e\u0440\u0430 \u0442\u0435\u0445\u043d\u0438\u0447\u0435\u0441\u043a\u0438\u0445 \u043d\u0430\u0443\u043a (Doctor of Science)", "7.\tInfinite Polyiodide Chains in the Pyrroloperylene\u2013Iodine Complex: Insights into the Starch\u2013Iodine and Perylene\u2013Iodine Complexes Sheri Madhu, Hayden A. Evans, Vicky V. T. Doan-Nguyen, John G. Labram, Guang Wu, Michael L. Chabinyc, Ram Seshadri,* and Fred Wudl* anie_2016", "8. Zheng, Y.-Y., Feng, K.-X., Xia, A.-B., Liu, J., Tang, C.-K., Zhou, Z.-Y., & Xu, D.-Q. Merging catalyst-free synthesis and iodine catalysis: one-pot synthesis of dihydrofuropyrimidines and spirodihydrofuropyrimidine pyrazolones. RSC Advances, (2019). 9 (17), 9770\u20139776. doi:10.1039/c9ra01665a", "9. Farebrother, J., Zimmermann, M. B., & Andersson, M. Excess iodine intake: sources, assessment, and effects on thyroid function. Annals of the New York Academy of Sciences. (2019). doi:10.1111/nyas.14041", "10. Wang, Z. Innovation of hypervalent(iii) iodine in the synthesis of natural products. New Journal of Chemistry, (2021). 45 (2), 509\u2013516. doi:10.1039/d0nj05078d", "11. Separation of iodine contained in uchkyzil groundwater on the basis of hexamethylentetramine and physico-chemical analysis of the composition. Uralov N.B.,Turayev Kh.Kh., Normurodov B.A., Karimov M.U.. Scientific Bulletin of NamSU- 2023"]}

Khaudak (Uzbekistan, Surkhandarya Region) groundwater contains high concentrations of various salts, and iodine ions are present in the form of potassium iodide. They are first oxidized under the influence of special oxidizers. Free iodine was precipitated by forming a complex on the basis of starch and its composition was observed using the scanning electron microscopy (SEM) method. According to it, it was proposed that a complex compound with starch iodide was formed.

Keywords

Khaudak underground brines, Uzhkyzil underground brines, iodine, petroleum waters, potassium iodide, potassium iodate, hexamethylenediamine, scanning electron microscopy, infrared spectroscopy.

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