Sodium‐ion batteries as a prospective alternative to lithium‐ion batteries are facing the challenge of developing high‐performance, low‐cost and sustainable anode materials. Hard carbons are appropriate to store sodium ions, but major energy and environmental concerns during their fabrication process (i.e., high‐temperature carbonization) have not been properly assessed. Furthermore, the rational design of high‐performing hard carbon anodes is usually limited by the conventional direct carbonization of organic precursors. Here, the hydrothermal carbonization process is employed as a versatile pre‐treatment method of renewable precursors, followed by high‐temperature carbonization, for producing advanced hard carbon anodes. The critical role of hydrothermal pre‐treatment in regulating the structure for an optimized performance of hard carbon anodes is elucidated, while revealing the sodium‐ion …