Data for: "A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes"

Authors: Shivaraam, R A Keerthi; Keener, Megan; Modder, Dieuwetje K; Rajeshkumar, Thayalan; Zivçovic, Ivica; Scopelliti, Rosario; Maron, Laurent; +1 Authors

doi: 10.5281/zenodo.7801480 , 10.5281/zenodo.7801481

Data for: "A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes"

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Abstract

Low valent uranium can be stabilized via an unprecedented mechanism involving intramolecular ligand migration:the two-and three-electron reduction of the oxo-bridgedU(IV)/U(IV)complex,[{(Ph3SiO)3(DME)U}2(O)], yields formal “U(II)”/U(IV) and “U(I)”/U(IV) complexes,via ligand migration and formation of uranium-arene δ-bond interactions,that can transfer up to threeelectrons tosubstrates by restoring the original ligand arrangement.

{"references": ["https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202304051"]}

Related Organizations

École Polytechnique Fédérale de Lausanne EPFL
Switzerland

Keywords

redox-active ligands, uranium, siloxides, arenes, low valent uranium

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