These datasets accompany the following manuscript: Logozzo, L.A.*, Hosen, J.D., McArthur, J., and Raymond, P.A. Distinct drivers of two size fractions of operationally dissolved Fe in a temperate river. Limnology and Oceanography. *Corresponding Author: Laura A. Logozzo, laura.logozzo@uleth.ca Datasets: 1- Fe-DOM-EMMA-merged.xlsx: this dataset includes operationally dissolved (<0.22 µm), colloidal (0.02-0.22 µm), and soluble (<0.02 µm) DOC concentrations, total Fe concentrations, PARAFAC component scores <0.22 µm, and end-member mixing model scores <0.22 µm. Samples were collected approximately bi-weekly from the Connecticut River at Thompsonville from April 2018 to March 2020. 2- Loadest-merged.xlsx: this dataset includes LOADEST-modeled daily-average and monthly-average fluxes of operationally dissolved (<0.22 µm), colloidal (0.02-0.22 µm), and soluble (<0.02 µm) Fe, DOC <0.22 µm, and allochthonous-like DOC <0.22 µm. All methodology is described in the accompanied manuscript.