Raw data files for a manuscript "A Simple, Transition Metal Catalyst-Free Method for the Design of Complex Organic Building Blocks Used to Construct Porous Metal-Organic Frameworks". All files are organized by instrumental methods, except Figure 1 in the manuscript and Figure S1, S52 in the SI, plots for which are reported as separate files. The file headers contain the necessary information such as column designations, units, etc.

Part of this work was supported by the Swiss National Science Foundation under grant number 200021_188536. We acknowledge Gaznat for the financial support of J.E and Fondation Valery for the support of N.T.