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Simultaneously Enhanced Tenacity, Rupture Work, and Thermal Conductivity of Carbon Nanotubes Fibers by Raising Effective Tube Portion

Authors: Zhang, Xiao;

Simultaneously Enhanced Tenacity, Rupture Work, and Thermal Conductivity of Carbon Nanotubes Fibers by Raising Effective Tube Portion

Abstract

Although individual carbon nanotubes (CNTs) are superior as constituents to polymer chains, the mechanical and thermal properties of CNT fibers (CNTFs) remain inferior to synthetic fibers due to the failure of embedding CNTs effectively in superstructures. Conventional techniques resulted in a mild improvement of target properties while achieving parity at best on others. Here, a Double-Drawing technique is developed to rearrange the constituent CNTs in both mesoscale and nanoscale morphology. Consequently, the mechanical and thermal properties of the resulting CNTFs can simultaneously reach their highest performances with specific strength ~3.30 N/tex, work of rupture ~70 J/g, and thermal conductivity ~354 W/m/K, despite starting from low-crystallinity materials (IG:ID~5). The processed CNTFs are more versatile than comparable carbon fiber, Zylon and Dyneema. Based on evidence of load transfer efficiency on individual CNTs measured with In-Situ-Stretching-Raman, we find the main contributors to property enhancements are the increasing of the effective tube contribution, in addition to the known optimization on CNTs alignment and stacking.

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Keywords

fibres, tenacity, carbon nanotubes, carbon fibers, toughness, rupture, thermal conductivity, fibers, strength, carbon fibres, Raman, chlorosulfonic acid

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selected citations
These citations are derived from selected sources.
This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
BIP!Popularity provided by BIP!
influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
BIP!Influence provided by BIP!
impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
BIP!Impulse provided by BIP!
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