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ZENODO
Article . 1956
License: CC BY
Data sources: Datacite
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ZENODO
Article . 1956
License: CC BY
Data sources: ZENODO
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ZENODO
Article . 1956
License: CC BY
Data sources: Datacite
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THERMAL DECARBOXYLATION OF CHLOROBENZOIC ACIDS

descriptionPublicationkeyboard_double_arrow_right Article 31 Aug 1956 English Publisher:Zenodo
Authors: S. S. MUHAMMED; MISS AZIZ SIDDIQUI;

doi: 10.5281/zenodo.6579488 , 10.5281/zenodo.6579487

THERMAL DECARBOXYLATION OF CHLOROBENZOIC ACIDS

Abstract

Thermal decarboxylation of o-chloro- and 2-4-dichlorobenzoic acids in resorcinol solution follows SE2. mechanism. The activation energies, frequency factors and entropies of activation are: 32300 cals. mole -1, 6.76x1010 sec. -1 and _12.0 cals. deg.-1 for o-chlornbenzoic acid, and 27600 cals mole-1, 3.98X 109sec.-1 and _17.6 cals. deg.-1 for 2 :4-dichlorobenzoic acid.

Keywords

Chlorobenzoic acid, Carboxylation, Benzoic acid

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