SOME SIX-CO-ORDINATED COMPLEXES OF NICKEL(II) : NITRITO-AMMINES OF NICKEL(II)

Several nitrito-ammines of nickel(II) have been prepared, viz., Ni [o-C6H4(NH2)2]2 (NO2)2, Ni[C6H5 CH2NH2]4(NO2)2 and \(Ni_2[H_2NCH_2CH_2NH_2]_2(NO_2)_3(OH)\). These are all red in colour, insoluble in water and paramagnetic with a moment of about 3 Bohr magnetons. These are believed to be six-coordinated nickel(II) complexes, and a polynuclear structure has therefore been assigned to the ethylenediamine complex.

Keywords

Pyridine compound, COMPLEXES OF NICKEL(II), Ethylenediamine compound

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