Dataset corresponding to the publication: Elucidation of radical- and oxygenate-driven paths in zeolite-catalyzed conversion of methanol and methyl chloride to hydrocarbons Alessia Cesarini,1† Sharon Mitchell,1† Guido Zichittella,1†* Mikhail Agrachev,2 Stefan P. Schmid,2 Gunnar Jeschke,2 Zeyou Pan,3 Andras Bodi,3 Patrick Hemberger,3* and Javier Pérez‑Ramírez1* 1 Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 1, 8093 Zurich, Switzerland, 2 Laboratory of Physical Chemistry, Department of Chemistry and Applied Biosciences, ETH Zurich, Vladimir-Prelog-Weg 2, 8093 Zurich, Switzerland, 3 Laboratory of Synchrotron Radiation and Femtochemistry, Paul Scherrer Institute, 5232 Villigen PSI, Switzerland, †These authors contributed equally, listed alphabetically. *Corresponding author. E-mails: zguido@mit.edu, patrick.hemberger@psi.ch, jpr@chem.ethz.ch.