Downloads provided by UsageCounts
Earlier researches on the transformations of terpineol with fused potassium hydrogen sulphate, aq. oxalic acid, sulphuric-acetic acid mixture and \(\gamma\)-alumina have been repeated, and in the reaction mixtures, α-terpinene, limonene and saturates have been quantitatively estimated. Reactions of terpineol, catalysed by iodine and boric acid, have been examined, and iodine has been found to be an excellent and quick agent for dehydrating terpineol. For eliminating α-terpinene in terpene mixtures, warming with maleic anhydride is shown to be a better route than agitating with cold Beckmann's chromic acid mixture. Bromination of terpinolene by Baeyer's technique has been improved, the essential change being the precipitation of the tetrabromide by addition of cold methanol. This modification avoids the Formation of oily products. No clean-cut elimination path for terpineol is revealed excepting in dehydrations with potassium hydrogen sulphate and alumina, wherein dl-limonene and terpinolene respectively are obtained as major reaction products. In all other cases, there result monocyclics containing α-terpinene, terpinolene, limonene and saturates including p-cymene, in varying proportions. A mechanism is proposed to account for the reaction products and to explain how terpineol can furnish both terpinolene and limonene with equal facility.
Dehydration, TERPENES, Methyl groups
Dehydration, TERPENES, Methyl groups
| citations The total number of citations received by all articles of the researcher of interest. | 0 | |
| popularity This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network. | Average | |
| influence This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically). | Average | |
| impulse This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network. | Average |
| views | 6 | |
| downloads | 5 |

Views provided by UsageCounts
Downloads provided by UsageCounts