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Infrared spectra, both fundamental and overtones of N-H band, of aniline, methylaniline, diphenyklamine, and indole have been studied in structurally different solvents. The validity of the K.B.M. equation has been tested in the case of indole, using the binary solvent CS2 - bexanen. The observed shifts, both blue and red, are explained in terms of intermolecular hydrogen bonding and localized electrostatic interaction! which are related with the polarisability of the solvent moloculea.
Infrared Spectra, Solvent Effect, electrostatic
Infrared Spectra, Solvent Effect, electrostatic
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