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ZENODO
Article . 1967
License: CC BY
Data sources: Datacite
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ZENODO
Article . 1967
License: CC BY
Data sources: Datacite
image/svg+xml art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos Open Access logo, converted into svg, designed by PLoS. This version with transparent background. http://commons.wikimedia.org/wiki/File:Open_Access_logo_PLoS_white.svg art designer at PLoS, modified by Wikipedia users Nina, Beao, JakobVoss, and AnonMoos http://www.plos.org/
ZENODO
Article . 1967
License: CC BY
Data sources: ZENODO
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A Study of Competitive and Consecutive Second Order Reactions : N-Alkylation of Amines by Methyl Iodide

descriptionPublicationkeyboard_double_arrow_right Article 31 May 1967 English Publisher:Zenodo
Authors: P. S. Radhakrishna Murti; G. P. Panigrahi;

doi: 10.5281/zenodo.6475440 , 10.5281/zenodo.6475441

A Study of Competitive and Consecutive Second Order Reactions : N-Alkylation of Amines by Methyl Iodide

Abstract

The kinetics of alkylation of aniline, methyl aniline and dimethyaniline by methyl iodide have been determined in nitrobenzene. The mechanism of the process has been discussed. Second order process has been observed with secondary and tertiary amines, presumably monoalkylation is occurring. In the case of aniline, a consecutive second order process has been noted indicating dialkylation. Frost-Schwemer treatment has been utilized to compute the second order rate constants. This is the first kinetic report of dialkylatioa in the case of aniline and mono-alkylation in the case of secondary amines.

Keywords

Nitrobenzene, Methyl, Monoalkylation

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This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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