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Crategolic (Maslinic) acid (Ia) has been converted to olean-12-en-2\(\propto\),3β-diacetoxy-28-al (le) by Rosenmund reduction of the acid chloride (Id) and by reductive desulphurisation of the berizylthiol ester (Ih). The aldehyde (Ie) has been reduced by Huang-Minlon's method to the hitherto unknown olean-12-en-2\(\propto\),3β-diol-(If).
oxygen function, Crategolic Acid
oxygen function, Crategolic Acid
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