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Article . 1970
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Kinetics of the Base·Catalysed Condensation of Acetophenone with Benzaldehydes : A Quantitative Separation of Inductive, Resonance and Steric Effects

Authors: P. L. Nayak; M. K. Rout;

Kinetics of the Base·Catalysed Condensation of Acetophenone with Benzaldehydes : A Quantitative Separation of Inductive, Resonance and Steric Effects

Abstract

The rate of base-catalysed condensation of acetophenone with substituted benzaldehydes has been studied in 90% alcohol. The reaction was first-order in each component. The Arrhenius parameters have been discussed. The applicability of Hammett equation has been studied. A quantitatiye separation of the inductive, resonance and steric effects has been attempted. The mechanism has been discussed.

Keywords

Resonance and Steric Effects, Kinetics of the Base·Catalysed

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This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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