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National Research Centre, Dokki-Cario, Egypt Received 13 March 1972 The action of triphenylphosphine and triisopropyl phosphite on 9-diazothioxanthene (I) was found to give different products depending upon the experimental conditions. 9-Chlorothioxanthene (VIIa) and 9-9-dichlorothioxanthene (VIIb) react with trialkyl phosphites to give the corresponding phosphonate derivatives VIIc-e and VIIg-i. Diphenylphosphinodithioic acid affects the conversion of VIIb into thioxanthene-9- thione (IX).
Organophosphorus Compounds, Phosphites, Diphenylphosphinodithioic
Organophosphorus Compounds, Phosphites, Diphenylphosphinodithioic
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