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Article . 1987
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Article . 1987
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Article . 1987
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Article . 1987
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ZENODO
Article . 1987
License: CC BY
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ZENODO
Article . 1987
License: CC BY
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Claim

Kinetics of Oxidation of L(—)β -Phenylalanine by Cerium(IV) in the Presence of Manganese(II) Ions

descriptionPublicationkeyboard_double_arrow_right Article 28 Feb 1987 English Publisher:Zenodo
Authors: B. L. KHANDIA; V. K. VAIDYA; S.C. AMETA;

doi: 10.5281/zenodo.6199082 , 10.5281/zenodo.6217430 , 10.5281/zenodo.6199081 , 10.5281/zenodo.6217429

Kinetics of Oxidation of L(—)β -Phenylalanine by Cerium(IV) in the Presence of Manganese(II) Ions

Abstract

Department of Chemistry, M. L. V. Government College, Bhilwara-311 001 Manuscript received 3 June 1986, revised 19 November 1986, accepted 3 January 1987 Oxidation of L(-)β-phenylalanine by cerium(IV) sulphate In the presence of manganese(II) ions has been found to be first order in both, oxidant and L(-),β-phenylalanine concentrations. Various hypotheses for the mechanism of acid catalysis have been tested. The energy and entropy of activation have been calculated as 15.74 kcal mol-1 and -18.24 kcal mol-1 K-1, respectively. A tentative mechanism has been proposed in consisteot with the experimental data.

Keywords

Solutions, cerium, amino acids, hydroxide, oxidative, sulphuric acid, solution, sulphate

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