Department of Chemistry. Banaras Hindu University, Varanasi-221 005 Manuscript received 27 November 1989, revised 31 October 1990. accepted 16 January 1991 IN continuation of our earlier work 1 on the cathodic reduction of some simple aliphatic oximes to the corresponding primary amine, we describe here the preparative utility of the cathodic reduction of oxime of some cycloalkanones, 1 ,2-diones and benzoin. The cathodic reduction of these is hitherto unreported. The polarographic studies of reduction of some other oximes in solution has been reported earlier 2,3.