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Kinetics of the Acid-mediated Dissociation of Mixed Chelate Complexes Aquation of Bis(acetylacetonato )ethylenediamine and Acetylacetonatobis( ethylenediamine )cobalt(III) Complexes

Name: Kinetics of the Acid-mediated Dissociation of Mixed Chelate Complexes Aquation of Bis(acetylacetonato )ethylenediamine and Acetylacetonatobis( ethylenediamine )cobalt(III) Complexes
Creator: ASIM KUMAR MAJEE
Keywords: Kinetics, cobalt, Mixed

descriptionPublicationkeyboard_double_arrow_right Article 30 Apr 1997 English Publisher:Zenodo

Authors: ASIM KUMAR MAJEE;

doi: 10.5281/zenodo.5880713 , 10.5281/zenodo.5880712

Kinetics of the Acid-mediated Dissociation of Mixed Chelate Complexes Aquation of Bis(acetylacetonato )ethylenediamine and Acetylacetonatobis( ethylenediamine )cobalt(III) Complexes

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Abstract

Department of Chemistry, Manipur University, Canchipur-795 003 Manuscript received 19 may 1995, revised 13 December 1995, accepted 15 December 1995 Mechanisms of the acid-mediated dissociation of two mixed chelate complexes, bis(acetylacetonato)ethylenediamine and acetylacetonatobis(ethylenediamine)cobalt(III) ions have been investigated spectrophotometrically. In the presence of perchloric acid the first complex dissociates to cobaltous ion, free ethylenediamine, free acetylacetone and oxidised products of acetylacetone. The dissociation follows an acid-assisted path. Rate constant (kobs) for the complexes have been evaluated. A mechanism has been proposed for the first complex.

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Kinetics, cobalt, Mixed

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