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Spectrophotometric determination of platinum(IV) using anthranilic acid

Authors: C. H. Raghavan Nambiar; B. Narayana; N. V. Sreekumar; R. A. Nazareth; N. Gopalakrishna Bhat;

Spectrophotometric determination of platinum(IV) using anthranilic acid

Abstract

Department of Studies in Chemistry, Mangalore University, Mangalagangotri-574 199, India E-mail : nbadiadka@yahoo.co.uk Fax : 91-824-287367 Manuscript received 11 July 2001, revised 22 January 2002, accepted 16 March 2002 A rapid and sensitive spectrophotometric method for the determination of PtIV with anthranilic acid is described. Anthranilic acid reacts with PtIV at pH 3.0 to give a pink coloured complex, which shows λmax at 372 nm. Sandell's sensitivity and molar absorptivity of the complex are 5.6 X 10-3 µg cm-2 and 3.41 x 104 dm3 mol-1 cm-1, respectively. The effect of foreign ion and other experimental variables are studied. PtIV has been successfully determined in synthetic solutions.

Keywords

ion, spectrophotometric method

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