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Article . 2003
License: CC BY
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Article . 2003
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Syntheses, magnetic and spectral studies of the coordination compounds of polystyrene-anchored dibasic tridentate Schiff base

descriptionPublicationkeyboard_double_arrow_right Article 31 Jan 2003 English Publisher:Zenodo
Authors: D. Kumar; A. Syamal; P. K. Gupta;

doi: 10.5281/zenodo.5835329 , 10.5281/zenodo.5835328

Syntheses, magnetic and spectral studies of the coordination compounds of polystyrene-anchored dibasic tridentate Schiff base

Abstract

Department of Chemistry. Regional Engineering College. Kurukshetra-136 119, India E-mail : dkumar_reck@ yahoo.corn Fax : 91-01744-238050 Manuscript received 20 February 2002, revised 19 August 2002. accepted 29 October 2002 Several new polystyrene-anchored coordination compounds of the types [PSCH2-LMn.3DMF], [PSCH2-LFeC1.2DMF], [PSCH2-LCo. 3DMF], [PSCH2-LCu.DMF], [PSCH2-LZn.DMF], [PSCH2-LZr(OH)2.2DMF], [PSCH2-LMoO2.DMI], [PSCH2- LCd.DMF] and [PSCH2-LUO2.DMF] (where, PSCH2-LH2 is polystyrene-anchored dibasic tridentate Schiff base obtained from the condensation of 3-formylsalicylic acid and 4-amino-5-inercapto-3-methyl-1,2,4-triazole) have been synthesized by the reaction of metal salt/metal coordination compound with PSCH2-LH2. The MnII, FeIII, CoII, Nill and Cull compounds are paramagnetic while ZnIV, ZrIV, MoVI, CdII and UVI compounds are diamagnetic. The Cull compound is square-planar, ZnIl and CdII compounds are tetrahedral, FeIII, CoII, NiII, MoVI and UVI compounds are octahedral, and ZrIV compound is pentagonal bipyramidal.

Keywords

spectral studies, polystyrene-anchored dibasic tridentate Schiff base, retlectance spectrum, coordination compound

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