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Article . 2004
License: CC BY
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Article . 2004
License: CC BY
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Article . 2004
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Apparent molar volumes and adiabatic compressibilities of L-glycine in aqueous solutions of (CH3)4NI, NaBr and NaI at 298.15 K

Authors: Amalendu Pal; Suresh Kumar;

Apparent molar volumes and adiabatic compressibilities of L-glycine in aqueous solutions of (CH3)4NI, NaBr and NaI at 298.15 K

Abstract

Department of Chemistry, Kurukshetra University, Kurukshctra-136 119. India E-mail : palchem@sify.com Manuscript received 27 July 2004 The densities and sound speeds of L-glycine in aqueous (CH3)4Nl, NaBr and NaI are reported at 298.15 K. These data are used to derive apparent molar volumes \(V_\phi\), and compressibilities \(K_{\phi,S}\)· Partial molar volumes \(V^0_\phi\) and partial molar adiabatic compressibilities \(K^0_{\phi,S}\) of L-glycine at infinite dilution were evaluated. These v:Jlucs are required for calculating hydration number nH of L-glycine. Transfer volumes \(ΔV_\phi^0\) and transfer adiabatic compressibilities \(ΔK^0_{\phi,S}\) at infinite dilution from water to aqueous electrolyte solutions have been calculated. Transfer parameters have been interpreted in terms of solutecosolute interactions on the basis of a cosphere overlap model.

Keywords

molar volumes, Salt solutions, solvent

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This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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