The raw 4D-SCED and 4D-STEM (NBD) datasets in our paper: Seeing Structural Evolution of Organic Molecular Nano-crystallites Using 4D Scanning Confocal Electron Diffraction https://arxiv.org/abs/2110.02373v1 Dose-damage_RT_and_Cryo_DRCN5T_PCBM.zip - EF-Diff_cryo_0.16e_per_A2_per_frame.dm4 - EF-Diff_RT_0.14e_per_A2s_per_frame.dm4 Fig_2_SCED-vs-NB_DH6T.zip - 00.43.44 Spectrum image_1.dm4: raw 3D diffraction pattern stack (NBD) of size 512*512*2500, only converted file format, no other pre-processing applied - 00.54.07 Spectrum image_1.dm4: raw 3D diffraction pattern stack (SCED) of size 512*512*2500, only converted file format, no other pre-processing applied - STEM HAADF 0103.emd: Velox raw image of the region of interest acquired at the end of experiment. - STEM HAADF 0103 data.jpg: exported JPG image with databar from the above raw image file Fig_3n4_4D-SCED-vs-4D-NBD_DRCN5T_PCBM.zip - 1201 4D STEM Dataset SCED.dm4: pre-processed 4D-SCED dataset - 1209 4D STEM Dataset NBD.dm4: pre-processed 4D-STEM (NBD) dataset Fig_5_insitu_4D-SCED_datasets.zip - 1431 4D STEM Dataset.dm4: pre-processed 4D-SCED dataset @ RT - 1431 SI HAADF RT.emd: simultaneously acquired SCEM-ADF image and STEM-EDXS datacube - 1431 SI HAADF.jpg: exported JPG image of the SCEM-ADF image from the above file - 1455 4D STEM Dataset.dm4: pre-processed 4D-SCED dataset @ 100C - 1455 SI HAADF 100C.emd: simultaneously acquired SCEM-ADF image and STEM-EDXS datacube - 1455 SI HAADF.jpg: exported JPG image of the SCEM-ADF image from the above file - 1505 4D STEM Dataset.dm4: pre-processed 4D-SCED dataset @ 120C - 1505 SI HAADF 120C.emd: simultaneously acquired SCEM-ADF image and STEM-EDXS datacube - 1505 SI HAADF.jpg: exported JPG image of the SCEM-ADF image from the above file - 1516 4D STEM Dataset.dm4: pre-processed 4D-SCED dataset @ 140C - 1516 SI HAADF 140C.emd: simultaneously acquired SCEM-ADF image and STEM-EDXS datacube - 1516 SI HAADF.jpg: exported JPG image of the SCEM-ADF image from the above file - 1529 4D STEM Dataset.dm4: pre-processed 4D-SCED dataset @ 160C - 1529 SI HAADF 160C.emd: simultaneously acquired SCEM-ADF image and STEM-EDXS datacube - 1529 SI HAADF.jpg: exported JPG image of the SCEM-ADF image from the above file STEM-EELS_DRCN5T_PCBM_SVA_CS.zip - ADF Image (SI survey).dm4: simultaneously acquired STEM-ADF image - EELS Spectrum Image (high-loss).dm4: high-loss part of the DualEELS STEM-EELS dataset - EELS Spectrum Image (low-loss).dm4: low-loss part of the DualEELS STEM-EELS dataset STEM-EELS_DRCN5T_PCBM_SVA_CHCl3.zip - ADF Image (SI survey).dm4: simultaneously acquired STEM-ADF image - EELS Spectrum Image (high-loss).dm4: high-loss part of the DualEELS STEM-EELS dataset - EELS Spectrum Image (low-loss).dm4: low-loss part of the DualEELS STEM-EELS datase

financial support from Deutsche Forschungsgemeinschaft (DFG) via - research training school GRK 1896: ``In-Situ Microscopy with Electrons, X-rays and Scanning Probes'', - Cluster of Excellence EXC 315 ``Engineering of Advanced Materials'' - SFB 953 ``Syntetic Carbon Allotropes''