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We report mechanistic insights of the bottom-up synthesis of nanodiamonds (NDs) from adamantane derivatives as molecular precursors. Thermal cracking of tetracosane below the decomposition temperature of adamantane, 1-adamantylamine or 2-azaadamantane revealed the initial steps of seeded diamond growth mechanism based on pyrolysis studies.
growth mechanism, nanodiamonds, molecular precursors, high pressure high temperature (HPHT)
growth mechanism, nanodiamonds, molecular precursors, high pressure high temperature (HPHT)
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