This data set includes the RAW DATA of the publication. ABSTRACT: A record large amorphous rotor bearing an intricate 3D-geometry is produced through additive manufacturing via selecting laser melting using a powder of a traditional bulk metallic glass-forming composition of the Fe-Si-Cr-B-C system. Not only does this technique overcome the technical limitations characteristic of casting processes for amorphous alloys, but the possibility to print complex 3D geometries is expected to greatly facilitate the channeling of the magnetic flux, when such component is used as a rotor in an electric machine. The as-built part is characterized in comparison to the powder material as well as as-spun ribbons using a wide range of complementary techniques, including synchrotron x-ray diffraction, calorimetry, electron microscopy as well as room temperature ferromagnetic and hardness testing. The built part has extraordinarily high values of hardness (877 HV) and remarkable high magnetic susceptibility (9.17). This latter feature leads to a better magnetic response in the presence of an external magnetic field evidenced by a faster approach to saturation. The coercivity is small (0.51 kA/M) and the magnetic saturation relatively high (1.29 T). In addition, a large anisotropic effect on the magnetization reaction in connection with the partial crystallization in the melt pool areas is investigated experimentally.