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The Wurtz-Fittig coupling reaction of 2,3-dichloronorbornene with sodium and chlorotrimethylsilane

Authors: Hari Prasad, S.; Nagendrappa, G.;

The Wurtz-Fittig coupling reaction of 2,3-dichloronorbornene with sodium and chlorotrimethylsilane

Abstract

Department of Studies in Chemistry, Central College Campus, Bangalore University, Bangalore-560 00 I, India E-mail : hariprasad@bub.ernet.in Manuscript received 28 July 2010, revised 12 May 20Jl, accepted 20 June 2011 The Wurtz-Fittig coupling reaction of 2,3-dichloronorbornene (1) with sodium and chlorotrimethylsilane in anhydrous THF solvent is reported. The novel reaction affords 2,3-bis(trimethylsilyl)norbornene (2), along with a small amount of reductive carbon-carbon ring cleaved product (3'-trimethylsilylcyclopentanyl)-l-trimethylsilylacetylene (3).

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India
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Wurtz-Fittig coupling reaction, Chemistry, dianionic synthons, 2,3-bis(trimethylsilyl)norbornene, Cyclic dianions, reductive carbon-carbon bond cleavage

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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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