Massive stars are often found to be in pairs. This configuration is both a blessing and a curse. From it, we can estimate their exact properties such as their masses but the interactions that result during their life considerably affect the way that the stars evolve. To understand how the stars evolve when they are in pair and what are the effects of these interactions on the stellar properties, we undertook a large study of more than 60 massive binaries at Galactic and LMC metallicities using spectral disentangling, atmosphere modelling and light curve fitting to determine their stellar parameters, and surface abundances. This unique dataset is the largest sample of binaries composed of at least one O-type star to be studied in such a homogeneous way. It allows us to give strong observational constraints to test theoretical binary evolutionary tracks, to probe rotational and tidal mixings and mass transfer episodes.

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