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Al2O3 supported-FeIII Schiff base complexes : Syntheses, characterizations and their applications in various oxidation reactions

Authors: Sourav Chatterjee; Priyabrata Banerjee; Dipankar Sukul; Tanmay Chattopadhyay;

Al2O3 supported-FeIII Schiff base complexes : Syntheses, characterizations and their applications in various oxidation reactions

Abstract

Department of Chemistry, Panchakot Mahavidyalaya, Purulia-723 121, West Bengal, India Department of Surface Engineering and Tribology, CMERI, Durgapur-713 209, West Bengal, India Department of Chemistry, NIT, Durgapur-713 209, West Bengal, India E-mail : tanmayc2003@gmail.com Manuscript received 21 october 2016, revised 06 January 2017, accepted 21 February 2016 Three mononuclear asymmetric FeIII-Schiff base complexes, namely FeL1Cl , FeL2Cl and FeL3Cl were prepared. These complexes were loaded over neutral active alumina to prepare alumina supported three heterogeneous catalysts, namely Ct-I, Ct-II and Ct-III. The catalysts were characterized by UV-Vis and FT-IR spectroscopy, thermogravimetric analysis and FE-SEM study. Finally, these catalysts have been studied for the oxidation of different types of organic substrate in the presence of hydrogen peroxide and appear to be easily recyclable.

Keywords

oxidation, heterogeneous catalysts, H2O2, Schiff base complexes, alumina

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This is an alternative to the "Influence" indicator, which also reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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popularity
This indicator reflects the "current" impact/attention (the "hype") of an article in the research community at large, based on the underlying citation network.
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influence
This indicator reflects the overall/total impact of an article in the research community at large, based on the underlying citation network (diachronically).
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impulse
This indicator reflects the initial momentum of an article directly after its publication, based on the underlying citation network.
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