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ZENODO
Dataset . 2016
License: CC BY
Data sources: Datacite
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ZENODO
Dataset . 2016
License: CC BY
Data sources: ZENODO
Claim

Effect Of Ionic Radii On The Curie Temperature In Ba1-X-Ysrxcaytio3 Compounds

Research datakeyboard_double_arrow_right Dataset 31 May 2016Publisher:Zenodo
Authors: Berenov, Andrey; Le Goupil, Florian; Alford, Neil;

doi: 10.5281/zenodo.53983

Effect Of Ionic Radii On The Curie Temperature In Ba1-X-Ysrxcaytio3 Compounds

Abstract

A series of Ba1-x-ySrxCayTiO3 compounds were prepared with varying average ionic radii and cation disorder on A-site. All samples showed typical ferroelectric behavior. A simple empirical equation correlated Curie temperature, TC, with the values of ionic radii of A-site cations. This correlation was related to the distortion of TiO6 octahedra observed during neutron diffraction studies. The equation was used for the selection of compounds with predetermined values of TC. The effects of A-site ionic radii on the temperatures of phase transitions in Ba1-x-ySrxCayTiO3 were discussed.

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