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In some recent articles in the literature (1),(2) the Schrodinger equation: p*p/2m W(x) + V(x) W(x) = E W(x) ((1)) is replaced with an equation using a relativistic momentum operator: [sqrt(p*p + m*m) - m] W(x) + V(x)W(x) = E W(x) ((2)) The first operator on the LHS of ((2)) is then expanded in powers of 1/(m*m). Next, p is replaced with hbar/i d/dx (or gradient in 3D) and perturbation theory used. In this note, we consider p*p as being a conditional average given by: p*p= [Integral dp f(p) exp(ipx) p*p ] / [Integral dp f(p) exp(ipx)] ((3)) The denominator is the wavefunction W(x). This result should hold for the nonrelativistic case. In the relativistic case, p is replaced everywhere with prel where prel= p/ sqrt(1-p*p/(m*m)) prel*prel = Integral dprel p*p (1+ p*p/(m*m)) f(prel) exp(iprel x) ((4)) And W(x) = Integral dprel f(prel) exp(iprel x) ((5)) To first order, we argue that Integral dprel f(prel) exp(iprel x) = Integral dp f(p) exp(i p x), but Integral p*p f(prel) dprel exp(i prel x) contributes a term . For higher orders, even Integral dprel f(prel) exp(i prel x) contributes. Thus, we try to argue that one does not only have a change in the prel*prel operator, but one must consider changes of prel within Integral dprel f(prel) exp(iprel x) itself. Thus, perturbation theory may not be enough in such cases.
relativistic corrections, Fourier series, perturbation theory
relativistic corrections, Fourier series, perturbation theory
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